THE APPLICATION OF QUANTUM MECHANICS TO CERTAIN CASES OF HOMOGENEOUS CATALYSIS. I
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چکیده
منابع مشابه
The Application of Quantum Mechanics to Certain Cases of Homogeneous Catalysis. I
1. The activation energy for the hydrolytic breaking of a peptid linkage has been calculated from quantum mechanical considerations. 2. The relative catalytic effects of H(+) and OH(-) and the mechanism of these effects have been calculated and discussed. 3. These effects are both qualitatively and semiquantitatively in agreement with experiment.
متن کاملThe Application of Quantum Mechanics to Certain Cases of Homogeneous Catalysis
(A) In a previous paper (1) the catalytic effect of H + and OHions on the hydrolytic splitting of the C N linkage was investigated by means of quantum mechanical considerations. In this paper will be reported investigations as to the effect of foreign rigid dipoles on the energy of the activated configurations, and thus on the energy of activation. If the latter is lowered a positive catalytic ...
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(A) In a previous paper (1) the catalytic effect of H + and OHions on the hydrolytic splitting of the C N linkage was investigated by means of quantum mechanical considerations. In this paper will be reported investigations as to the effect of foreign rigid dipoles on the energy of the activated configurations, and thus on the energy of activation. If the latter is lowered a positive catalytic ...
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ژورنال
عنوان ژورنال: Journal of General Physiology
سال: 1934
ISSN: 1540-7748,0022-1295
DOI: 10.1085/jgp.18.2.171